Solution of Nonlinear Polarization Boundary Conditions
DOI:
https://doi.org/10.14713/ejbe.v1i3.767Abstract
An efficient algorithm for solving multiple reaction electrochemical polarization equations is presented. The boundary integral formulation for the electric field (Laplace equation) conveniently provides a direct relationship between potential and current at the electrode surfaces, which can then be coupled to the nonlinear polarization boundary conditions. As a consequence, a successful Gauss-Seidel type iteration, incorporating a nonlinear solve at each step, can be developed. Results are presented for the modeling multiple chemical reactions in an electrospray emitter tube.Downloads
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2007-10-25
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